Product ID:LP GAS PROPANE WITH ODORANT, 143200-00002
MSDS Date:08/15/1989
FSC:6830
NIIN:00N018129
MSDS Number: BLXSL

EXXON CO USA

HOUSTON, TX 77252-2180
US

Emergency Phone: 713-656-3424

Cage: 29667

EXXON COMPANY U.S.A.

2180 HOUSTON, TX 77252-2180 US

Telephone: 713-656-5949 / 713-656-3424

Cage: 29700

PROPANE; (LIQUIFIED PETROLEUM GAS)

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: SIMPLE ASPHYXIANT

OF PROPANE, AN ODORANT/STENCHING AGENT, IS ADDED TO

RTECS: 9999999ZZ

OTHER ODORANT, MAY NOT BE EFTIVE IN ALL CASES ALL THE

RTECS: 9999999ZZ

SUCH CNTNRS TO HEAT/FLAME/SPKS/STATIC ELEC/OTHER

RTECS: 9999999ZZ

DEATH. DO NOT ATTEMPT TO CLEAN SINCE RESIDUE IS DFCLT

RTECS: 9999999ZZ

SKIN THORO AFTER CONTACT, BEFORE BREAKS &

RTECS: 9999999ZZ

GAS AT AMBIENT TEMPERATURE.

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:ORAL(RAT)>5 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HLTH STUDIES HAVE SHOWN MANY PETRO
HYDROCARBS & SYNTH LUBRICANTS POSE POTNTL HUMAN HLTH RISKS WHICH
MAY VARY FROM PERS TO PERS. AS PREC, EXPOS TO LIQS/VAPS/MISTS/FUMES
SHOULD BE MINIMIZED. OVEREXP MAY CAUSE GASPING, DISORIENTATION,
UNCON &POSS DEATH. TREAT FOR ASPHY. EXPOS TO RAPIDLY EXPANDING GAS/
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:VAPORIZING LIQ MAY CAUSE FROSTBITE
(COLD BURN). SKIN:PRLNG/RPTD CNTCT TENDS TO REMOVE OILS, POSS
LEADING TO IRRIT & DERM, NOT CORR/IRRIT. EYES:MAY CAUSE IRRIT.
INHAL:LOW ORDER OF ACUTE TOX. S IMPLE ASPHY. INHAL OF EXHST FROM
BURNING, SUCH AS CO, MAY CAUSE DEATH @ HIGH CONC. EXPOS TO EXHST
SHOULD BE MINIMIZED.
Medical Cond Aggravated by Exposure:NONE RECOGNIZED.

First Aid:EYE:IMMED FLUSH EYES W/POTABLE WATER FOR MINIMUM OF 15 MIN.
SEEK ASSIST FROM MD . SKIN:FLUSH W/COPIOUS AMTS OF WATER. IMMED
CNTCT MD FOR TREATMENT OF FROSTBITE. INHAL:REMOVE FROM EXPOS & CALL
MD IMMED. IF BRTHG IRREG/STOPPED, START RESUSCITATION, ADMIN O2,
IF AVAIL. INGEST:DO NOT INDUCE VOMIT, CALL MD IMMED.

Flash Point Method:TCC
Flash Point:-0F,-18C
Lower Limits:2.1%
Upper Limits:9.5%
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. STOP FLOW OF GAS. USE H20 TO KEEP FIRE-EXPOS CNTNRS COOL & TO
PROTECT PERS EFFECTING SHUTOFF. IF (SUPDAT)
Unusual Fire/Explosion Hazard:LIQ IS VOLAT & GIVES OFF INVISIBLE VAPS.
EITHER LIQ/VAP MAY SETTLE IN LOW AREAS/TRAVEL SOME DIST ALONG
GROUND/SURF TO IGNIT SOURCE WHERE THEY MAY IGNITE(SUPDAT)

Spill Release Procedures:SHUT OFF & ELIM ALL IGNIT SOURCES. KEEP PEOPLE
AWAY. MIN BRTHG VAPS & SKIN CNTCT. VENT CONFINED SPACES. OPEN
WINDOWS & DOORS. VERY HIGH VOLAT OF MATL WILL CAUSE EXTREMELY RAPID
EVAP & NO OTHER DISP ME TH IS NEEDED/SHOULD BE ATTEMPTED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DANGER:PROD IS COMPRESSED GAS. VERY
HIGH VOLAT OF MATL WILL CAUSE EXTREMELY RAPID EVAP. KEEP CNTNRS
CLSD WHEN NOT IN USE. AVOID CREATING STATIC ELEC.
Other Precautions:DO NOT FILL/STORE NEAR HEAT/SPKS/FLAME/STRONG
OXIDANTS. USE APPROP EQUIP. MIN BRTHG VAP/MIST. AVOID PRLNG/RPTD
CNTCT W/SKIN. EMPTY CNTNRS CONTAIN RESIDUE (LIQ &/VAP) & CAN BE
DANGEROUS. DO NOT PRESS/C UT/ WELD/SOLDER/DRILL/GRIND/EXPOS (ING 4

Respiratory Protection:USE NIOSH/MSHA APPROVED SUPPLIED-AIR RESPIRATORY
PROTECTION IN CONFINED OR ENCLOSED SPACES.
Ventilation:USE W/VENT SUFFICIENT TO PVNT EXCEEDING RECOMMENDED EXPOS
LIM/BUILDUP OF EXPLO CONC VAP IN AIR.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:CHEMICAL-RESISTANT APRON OR OTHER CLOTHING.
Work Hygienic Practices:REMOVE CONTAM CLTHG, WASH/DRY-CLEAN BEFORE
REUSE. REMOVE CONTAM SHOES & THORO CLEAN & DRY BEFORE REUSE.
CLEANSE (ING 6)
Supplemental Safety and Health
FIRE FIGHT PROC:LEAK/SPILL HAS NOT IGNITED, USE H20 SPRAY TO DISPERSE
GAS/VAP & TO PROT PERS ATTEMPTING TO STOP LEAK. MIN BRTHG
GASES/VAP/ FUMES/DECOMP PRODS. EXPLO HAZ:OR EXPLODE. EXTREMELY
FLAMM. KE EP PROD AWAY FROM INGIT SOURCES, SUCH AS HEAT/SPKS/PILOT
LIGHTS/ STATIC ELEC/OPEN FLAMES. BECAUSE OF HAZ NATURE (ING 2)

HCC:G2
Boiling Pt:B.P. Text:-49F,-45C
Melt/Freeze Pt:M.P/F.P Text:INGRED 7
Vapor Pres:208 @ 100F
Vapor Density:1.5
Spec Gravity:0.5
pH:NEUT
Evaporation Rate & Reference:GAS @ NORM AMBIENT CNDTNS
Solubility in Water:NEGILGIBLE; <0.1%
Appearance and Odor:VAPOR & LIQUID ARE COLORLESS; PRODUCT CONTAINS
STENCHING AGENT.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS SUCH AS LIQ CHLORINE, CONC O2, SODIUM HYPOCHLORITE OR
CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:FUMES, SMOKE, CARBON MONOXIDE,
ALDEHYDES & OTHER DECOMP PRODS, IN CASE OF INCOMPLETE COMBUSTION.

Waste Disposal Methods:SEE SPILL PROC. DISPOSE OF I/A/W ALL FEDERAL,
STATE & LOCAL REGULATIONS . ALL CNTNRS SHOULD BE DISP OF IN ENVIRON
SAFE MANNER & I/A/W GOVT REG.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.